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Dichloridobis(dimethyl sulfoxide-κO)diphenyltin(IV)

✍ Scribed by Sadiq-ur-Rehman, ;Saeed, Sadia ;Ali, Saqib ;Shahzadi, Saira ;Helliwell, Madeleine

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
847 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The geometry around the Sn atom of the title compound, [Sn(C 6 H 5 ) 2 Cl 2 (C 2 H 6 OS) 2 ], is distorted octahedral, with Sn-C and Sn-O distances lying in the ranges 2.139 (4)-2.156 (4) and 2.270 (2)-2.279 (2) A ˚, respectively. Molecules are linked by intermolecular C-HÁ Á ÁO and C-HÁ Á ÁCl hydrogen bonds, and by C-HÁ Á Á interactions with distances of 2.8 and 2.75 A ˚.

📜 SIMILAR VOLUMES

[N-(5-Chloro-2-oxidobenzylidene)-l-valin
[N-(5-Chloro-2-oxidobenzylidene)-l-valinato-κ3O,N,O′]diphenyltin(IV)
✍ Dong, Yan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 402 KB

The Sn atom of the title compound, [Sn(C~6~H~5~)~2~(C~12~H~12~ClNO~3~)], is in a distorted SnNC~2~O~2~ trigonal–bipyramidal geometry and forms five- and six-membered chelate rings with the tridentate ligand. One phenyl group is disordered over two positions with occupancy factors 0.58 (3):0.42 (3).

Dichlorido(dimethyl sulfoxide-κO)(1,10-p
Dichlorido(dimethyl sulfoxide-κO)(1,10-phenanthroline-5,6-dione-κ2N,N′)copper(II) dimethyl sulfoxide monohydrate
✍ Xu, Guang-Jun ;Xie, Ming-Jin ;Feng, Li ;Yan, Shi-Ping ;Liao, Dai-Zheng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 559 KB

The title compound, [CuCl 2 (C 12 was obtained by the reaction of 1,10-phenanthroline-5,6-dione (phendione) and CuCl 2 Á2H 2 O. The copper(II) ion is pentacoordinated in a distorted squarepyramidal environment. The water molecule connects the complex and a dimethyl sulfoxide solvent molecule by O-H