Diazidobis(1,7-phenanthroline)zinc(II)
✍ Scribed by Sun, Bai-Wang ;Du, Lin
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 306 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Zn(C 7 H 4 O 5 S)(C 12 H 8 N 2 ) 2 ]Á3H 2 O, the two crystallographically distinct Zn atoms are both coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from the carboxylate group in a distorted octahedral geometry. The 3-sulfonatobenzoate ligand o
The mononuclear structure of Zn(S 2 CN(CH 2 ) 4 ) 2 (4,7-Ph 2 -1,10-phenanthroline) shows the zinc atom in each of the two independent molecules comprising the asymmetric unit to exist in a distorted octahedral geometry defined by an N 2 S 4 donor set.
Single-crystal X-ray study T = 193 K Mean '(C±C) = 0.003 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.