Diazidobis(1,10-phenanthroline)iron(II)
✍ Scribed by Miao, Zhi-Xin ;Shao, Min ;Liu, Hong-Jiang ;Li, Ming-Xing
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 162 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.054 wR factor = 0.125 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, cis-[FeCl 2 (C 12 H 8 N 2 ) 2 ], the Fe atom has a distorted octahedral coordination composed of four N atoms from two phenanthroline groups and two Cl atoms. The crystal packing is stabilized by weakstacking of neighboring phenanthroline groups.
In the title compound, [Mn(NCO) 2 (C 12 H 8 N 2 ) 2 ], the Mn atom, on a twofold rotation axis, is chelated by the two phenanthroline ligands, with two cyanate groups in cis positions.