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Diastereoselective synthesis of 1,4-amino alcohols via 1,4-stereochemical control using sulfoximines

✍ Scribed by Stephen G. Pyne; Zemin Dong

Book ID: 104262006
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 206 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01223-x

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✦ Synopsis

A diastereoselective synthesis of 1,4-amino alcohols can be achieved from a highly diastereoselective reduction of a y-keto-vinyl sulfoximine followed by C-methylation and then a highly diastereoselective palladium(0) catalysed ailylic sulfoximine to allylic sulfinamide rearrangement with 1,4-stereochemical control from a remote hydroxyl group.

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