Diaquabis(1,1,4-trimethylthiosemicarbazide)nickel(II) dinitrate
✍ Scribed by Burrows, Andrew D. ;Harrington, Ross W. ;Mahon, Mary F.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 220 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Ni(C 2 H 8 N 2 ) 2 (H 2 O) 2 ](C 10 H 8 NO 3 S) 2 Á-2H 2 O, the Ni atom of the centrosymmetric cation has a distorted octahedral coordination geometry, and is bonded to four N atoms, from two diethylenediamine ligands, and to two water O atoms. Symmetry-related 4-aminonaphthal
The title compound, [Ni(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is isostructural with the manganese analogue. The Ni atom, which lies on a centre of inversion, is coordinated by two imidazole and two water ligands, as well as by the formylbenzoate groups, in an all-trans octahedral geometry.
In the title complex, [Ni(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 6 S)Á4H 2 O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in