Bis(1,1,5,5-tetramethyl-2-thiobiuretato)nickel(II)
✍ Scribed by Crane, Jonathan D ;Whittingham, Matthew
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 561 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The molecular structure of the title compound, (C 21 H 17 N 8 ) 2 [Ni(CN) 4 ], consists of two organic cations, C 21 H 17 N 8 + or [MTIT] + , and a centrosymmetric inorganic dianion, [Ni(CN) 4 ] 2À . In the crystal structure, the ions stack along the b axis and are connected by a number of C-HÁ Á ÁN
In the structure of the title compound, [PdCl 2 (C 5 H 10 N 2 ) 2 ], at 150 K, the Pd atom is situated on a centre of inversion. The geometry of the complex is similar to that of trans-bis(1benzylimidazole)dichloropalladium(II).
In the title complex, [Ni(C 12 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 O 6 S)Á4H 2 O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in