Diaquabis(ethylenediamine)nickel(II) bis(4-aminonaphthalene-1-sulfonate) dihydrate
✍ Scribed by Li, Ming-Tian ;Wang, Cheng-Gang ;Wu, Yu ;Fu, Xu-Cheng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 253 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Ni(C 2 H 8 N 2 ) 2 (H 2 O) 2 ](C 10 H 8 NO 3 S) 2 Á-2H 2 O, the Ni atom of the centrosymmetric cation has a distorted octahedral coordination geometry, and is bonded to four N atoms, from two diethylenediamine ligands, and to two water O atoms. Symmetry-related 4-aminonaphthalene-1sulfonate anions are antiparallel. The crystal structure is stabilized byinteractions and N-HÁ Á ÁO, O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds.
📜 SIMILAR VOLUMES
In the title compound, [Cu(C 2 H 8 N 2 ) 2 (H 2 O) 2 ](C 7 H 4 NO 4 ) 2 , the component complex cations and organic anions interact by way of N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds, leading to a layered structure. The Cu atom has site symmetry 1.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.044 wR factor = 0.074 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title complex, [Co(C 9 H 10 NO 2 ) 2 (C 6 H 6 N 2 O) 2 (H 2 O) 2 ]Á-2H 2 O, is monomeric with the Co atom situated on a crystallographic center of inversion. It contains two 4-(dimethylamino)benzoate (DMAB) and two nicotinamide (NA) ligands, and two coordinated and two uncoordinated water molecu