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Diaqua­bis(ethyl­enediamine)nickel(II) bis­(4-amino­naphthalene-1-sulfonate) dihydrate

✍ Scribed by Li, Ming-Tian ;Wang, Cheng-Gang ;Wu, Yu ;Fu, Xu-Cheng


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
253 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title complex, [Ni(C 2 H 8 N 2 ) 2 (H 2 O) 2 ](C 10 H 8 NO 3 S) 2 Á-2H 2 O, the Ni atom of the centrosymmetric cation has a distorted octahedral coordination geometry, and is bonded to four N atoms, from two diethylenediamine ligands, and to two water O atoms. Symmetry-related 4-aminonaphthalene-1sulfonate anions are antiparallel. The crystal structure is stabilized byinteractions and N-HÁ Á ÁO, O-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds.


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