The title compound, [Cd(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N)], is a molecular heteroleptic cadmium thiolate containing an additional 3,5-dimethylpyridine ligand. The Cd II ion is located at the centre of the trigonal bipyramid formed by five atoms, viz. two S, two O and one N. Molecules pack as discrete
Diamminebis(tri-tert-butoxysilanethiolato)cadmium(II) acetonitrile solvate
✍ Scribed by Dołęga, Anna ;Godlewska, Sylwia ;Baranowska, Katarzyna
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 369 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
metal-organic papers Acta Cryst. (2006). E62, m3407-m3409 Kropidłowska et al. [Cd(C 12 H 27 O 3 SiS) 2 (C 10 H 8 N 2 )] m3409
In the title compound, [Zn(C 12 H 27 O 3 SSi) 2 (C 5 H 8 N 2 )]ÁC 3 H 8 O, the Zn II centre is coordinated by the N atom of the 2ethylimidazole ligand and two S and two O atoms of the two thiolate ligands in a trigonal-bipyramidal geometry. The hydroxyl group of the propan-2-ol solvent molecule form
## Abstract NMR studies on the reaction of bis[bis(tri‐__tert__‐butoxysilanethiolato)cadmium(II)] with 3,5‐dimethylpyridine in benzene‐__d__~6~ and toluene‐__d__~8~ solutions provide clear evidence for the equilibrium character of formation of mixed S,N‐ligand cadmium complex. Copyright © 2007 John