Di-μ-methanolato-bis[(η4-tetrafluorobenzobarrelene)rhodium(I)]
✍ Scribed by García-Orduña, Pilar ;Mena, Inmaculada ;Casado, Miguel A. ;Lahoz, Fernando J.
- Book ID
- 114501162
- Publisher
- International Union of Crystallography
- Year
- 2012
- Tongue
- English
- Weight
- 390 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
The title complex, [Ir 2 (-Br) 2 (C 8 H 12 ) 2 ], displays a dinuclear structure with bridging Br atoms, generated by twofold symmetry. The coordination geometry around the Ir atom is pseudo-square-planar, involving two Br atoms and two 2 C C bonds. The Ir 2 (-Br) 2 core shows a bent geometry with a
The molecular structure of the title compound, [Ir 2 I 2 (C 8 H 12 ) 2 ], has C 2 symmetry. The dinuclear structure features two bridging I atoms and a bent geometry for the Ir 2 (-I) 2 core, with a hinge angle of 95.26 (1) .
The title complex, [Rh(C 7 H 8 )(C 4 H 8 O) 2 ]BF 4 , contains a rhodium(I) centre coordinated in a square-planar manner by two tetrahydrofuran molecules and the mid-points of the double bonds of an 4 -coordinated norbornadiene ligand.