The title complex, [Ir 2 (-Br) 2 (C 8 H 12 ) 2 ], displays a dinuclear structure with bridging Br atoms, generated by twofold symmetry. The coordination geometry around the Ir atom is pseudo-square-planar, involving two Br atoms and two 2 C C bonds. The Ir 2 (-Br) 2 core shows a bent geometry with a
Di-μ-iodido-bis[(η4-cycloocta-1,5-diene)iridium(I)]
✍ Scribed by Yamagata, Tsuneaki ;Nagata, Mitsuhiro ;Mashima, Kazushi ;Tani, Kazuhide
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 506 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The molecular structure of the title compound, [Ir 2 I 2 (C 8 H 12 ) 2 ], has C 2 symmetry. The dinuclear structure features two bridging I atoms and a bent geometry for the Ir 2 (-I) 2 core, with a hinge angle of 95.26 (1) .
📜 SIMILAR VOLUMES
In the title complex, [RhCl(C~8~H~12~)(C~24~H~32~N~2~O~6~)], the Rh atom is coordinated by a Cl atom, one C atom of the tetrahydropyrimidine ring and the two double bonds of cyclooctadiene. Each of the tetrahydropyrimidine and cyclooctadiene rings is puckered.
The title compound, [RhCl(C~8~H~12~)(C~6~H~13~NO)], which is of interest from the point of view of catalysis, crystallizes with two independent molecules in the asymmetric unit, which is the complete unit cell. Neither the Rh—Cl nor the Rh—N bond lengths deviate significantly from the corresponding