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Di-μ-bromido-bis[(η4-cycloocta-1,5-diene)iridium(I)]

✍ Scribed by Yamagata, Tsuneaki ;Nagata, Mitsuhiro ;Mashima, Kazushi ;Tani, Kazuhide

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 401 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807019769

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✦ Synopsis

The title complex, [Ir 2 (-Br) 2 (C 8 H 12 ) 2 ], displays a dinuclear structure with bridging Br atoms, generated by twofold symmetry. The coordination geometry around the Ir atom is pseudo-square-planar, involving two Br atoms and two 2 C C bonds. The Ir 2 (-Br) 2 core shows a bent geometry with a hinge angle of 101.58 (3) .

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