✦ LIBER ✦

Chlorido(η4-cycloocta-1,5-diene)[(S)-2-(methoxymethyl)pyrrolidine-κN]rhodium(I)

✍ Scribed by Dahlenburg, Lutz ;Treffert, Harald ;Heinemann, Frank W.

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 390 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807052920

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✦ Synopsis

The title compound, [RhCl(C~8~H~12~)(C~6~H~13~NO)], which is of interest from the point of view of catalysis, crystallizes with two independent molecules in the asymmetric unit, which is the complete unit cell. Neither the Rh—Cl nor the Rh—N bond lengths deviate significantly from the corresponding dimensions observed for closely related chloride–rhodium complexes in the literature. Individual molecules are interlinked through N—H...Cl hydrogen-bonding interactions.

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