In the title compound, [Na(C 5 H 5 NO) 4 ]BF 4 , each Na + ion, lying on an inversion centre, is octahedrally coordinated by four bridging and two terminal pyridone ligands, creating a cationic coordination polymer chain with tetrafluoroborate anions occupying the spaces between the chains.
(η4-Norbornadiene)bis(tetrahydrofuran-κO)rhodium(I) tetrafluoroborate
✍ Scribed by Braun, Wolfgang ;Calmuschi-Cula, Beatrice ;Salzer, Albrecht
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 184 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title complex, [Rh(C 7 H 8 )(C 4 H 8 O) 2 ]BF 4 , contains a rhodium(I) centre coordinated in a square-planar manner by two tetrahydrofuran molecules and the mid-points of the double bonds of an 4 -coordinated norbornadiene ligand.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 100 K Mean (C±C) = 0.007 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 -bis[(2,2 0 0 0 -bipyridinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 )bis[(1,10-phenanthrolinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)