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(η4-Norbornadiene)bis­(tetra­hydro­furan-κO)rhodium(I) tetra­fluoro­borate

✍ Scribed by Braun, Wolfgang ;Calmuschi-Cula, Beatrice ;Salzer, Albrecht


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
184 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title complex, [Rh(C 7 H 8 )(C 4 H 8 O) 2 ]BF 4 , contains a rhodium(I) centre coordinated in a square-planar manner by two tetrahydrofuran molecules and the mid-points of the double bonds of an 4 -coordinated norbornadiene ligand.


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In the title compound, [Na(C 5 H 5 NO) 4 ]BF 4 , each Na + ion, lying on an inversion centre, is octahedrally coordinated by four bridging and two terminal pyridone ligands, creating a cationic coordination polymer chain with tetrafluoroborate anions occupying the spaces between the chains.

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Single-crystal X-ray study T = 100 K Mean (C±C) = 0.007 A Ê R factor = 0.043 wR factor = 0.112 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.