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catena-Poly[[[bis­(2-pyridone-κO)sodium]-di-μ-2-pyridone-κ4O:O] tetra­fluoro­borate]

✍ Scribed by Owen, Gareth R. ;Haddow, Mairi F.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
326 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Na(C 5 H 5 NO) 4 ]BF 4 , each Na + ion, lying on an inversion centre, is octahedrally coordinated by four bridging and two terminal pyridone ligands, creating a cationic coordination polymer chain with tetrafluoroborate anions occupying the spaces between the chains.

📜 SIMILAR VOLUMES

Diaqua­tris(nitrato-κ2O,O′)bis­(4-pyrido
Diaqua­tris(nitrato-κ2O,O′)bis­(4-pyridone-κO)lanthanum(III)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 315 KB

In the mononuclear title compound, [La(NO 3 ) 3 (C 5 H 5 NO) 2 -(H 2 O) 2 ], the La III atom is ten-coordinate, with a coordination polyhedron made up of the O atoms of two 4-pyridone ligands, six O atoms of three O,O 0 -chelating nitrate groups and two water molecules, the polyhedron approximating