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Diaquatris(nitrato-κ2O,O′)bis(4-pyridone-κO)lanthanum(III)

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 315 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805035439

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✦ Synopsis

In the mononuclear title compound, [La(NO 3 ) 3 (C 5 H 5 NO) 2 -(H 2 O) 2 ], the La III atom is ten-coordinate, with a coordination polyhedron made up of the O atoms of two 4-pyridone ligands, six O atoms of three O,O 0 -chelating nitrate groups and two water molecules, the polyhedron approximating a dodecahedron. The molecule lies on a twofold rotation axis. A threedimensional network structure is formed by hydrogenbonding andstacking interactions.

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✦ Synopsis

Diaquatris(nitrato-κ2O,O′)bis(4-pyridone-κO)lanthanum(III)