Tris(nitrato-κ2O,O′)bis(1,10-phenanthroline-κ2N,N′)ytterbium(III)
✍ Scribed by Liu, Y.-F. ;Xia, H.-T. ;Yang, S.-P. ;Wang, D.-Q.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 494 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Tris(nitrato-j 2 O,O 0 0 0 )bis(1,10-phenanthrolinej 2 N,N 0 0 0 )ytterbium(III)
📜 SIMILAR VOLUMES
In the title complex, [Cu(C~8~H~5~O~3~)(NO~3~)(C~12~H~8~N~2~)(H~2~O)], the Cu^II^ atom adopts a distorted square-pyramidal coordination geometry with an O atom of the nitrate group occupying the apex of the pyramid. The complex molecules are linked into ribbons along the __a__ axis __via__ hydrogen
The title ternary mixed-ligand chromium(III) complex, [Cr(C~5~H~7~O~2~)(C~2~O~4~)(C~12~H~8~N~2~)]·3H~2~O, features a distorted octahedral geometry completed by three different bidentate chelating ligands, __viz__. 1,10-phenanthroline, acetylacetonate and oxalate. Complex molecules are linked by π–π
In the title compound, [Ce(C 6 H 4 NO 2 ) 3 (C 12 H 8 N 2 ) 2 (H 2 O) 2 ]Á-3H 2 O, the Ce III atom shows a capped trigonal prismatic N 4 O 5 coordination. The CeÐO and CeÐN bond distances are 2.390 (2)±2.517 (2) and 2.730 (3)±2.752 (3) A Ê , respectively.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.032 wR factor = 0.065 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.