Di-μ-iodo-bis{[methyltris(methylthiomethyl)silane-κ2S,S′]copper(I)}
✍ Scribed by Yim, Hing W. ;Rabinovich, Daniel ;Lam, Kin-Chung ;Golen, James A. ;Rheingold, Arnold L.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 251 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The central Zn atom in the structure of the title compound, [ZnCl 2 (C 4 H 10 S 2 )], exhibits a distorted tetrahedral geometry and is coordinated by two Cl and two S atoms, with ZnÐCl distances of 2.203 (2) and 2.212 (2) A Ê , and ZnÐS distances of 2.390 (2) and 2.459 (2) A Ê . The angles ClÐZnÐCl
The title complex, [Cu 2 I 2 (C 22 H 20 N 3 OP) 2 ]ÁCH 2 Cl 2 , has a dimeric structure with a central Cu 2 I 2 core formed about a twofold rotation axis. Each Cu I centre is coordinated by an N atom at the 8-position of 1,8-naphthyridine to give an approximately planar triangular coordination geome
The title compound, [Zn(C 12 H 10 N 2 O 2 S) 2 (C 2 H 6 OS)], is monomeric with the Zn atom in a ®ve-coordinate environment. The geometry of the polyhedron is distorted trigonal bipyramidal, with angles of the equatorial atoms about the central Zn atom in the range 77.84 (10)±126.66 (12) A Ê . The O