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Di-μ-chlorido-bis[(di-2-pyridyl disulfide-κ2N,N′)copper(I)]

✍ Scribed by Wang, Liang-Gui

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
598 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Cu 2 Cl 2 (C 10 H 8 N 2 S 2 ) 2 ], the asymmetric unit contains one and a half dinuclear copper complexes, one complex being arranged around an inversion center. In each complex, the Cu I atom is coordinated by two N atoms from one di-2-pyridyl disulfide ligand and two bridging Cl atoms, and has a distorted tetrahedral geometry.

Related literature

For general background, see: Kadooka et al. (1976a,b);

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✍ Koch, Christian ;Görls, Helmar ;Westerhausen, Matthias 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 949 KB

The title compound, [Li~2~Cl~2~(C~15~H~38~N~2~Si)~4~], is a centrosymmetric dimer. Each Li atom is coordinated in a distorted tetrahedral manner by two pyridyl rings and two chloride anions. Only one of the two symmetry-independent NH groups is involved in hydrogen bonding.