In the title complex, [Cu 2 Cl 2 (C 10 H 8 N 2 S 2 ) 2 ], the asymmetric unit contains one and a half dinuclear copper complexes, one complex being arranged around an inversion center. In each complex, the Cu I atom is coordinated by two N atoms from one di-2-pyridyl disulfide ligand and two bridgin
Di-μ-chlorido-bis({2-[(triisopropylsilyl)aminomethyl]pyridine-κN}lithium(I))
✍ Scribed by Koch, Christian ;Görls, Helmar ;Westerhausen, Matthias
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 949 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Li~2~Cl~2~(C~15~H~38~N~2~Si)~4~], is a centrosymmetric dimer. Each Li atom is coordinated in a distorted tetrahedral manner by two pyridyl rings and two chloride anions. Only one of the two symmetry-independent NH groups is involved in hydrogen bonding.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.023 wR factor = 0.060 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Di-l-chlorido-bis[(2-anilinobenzoatoj 2 O,O 0 0 0 )(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)]