𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Di-μ-chlorido-bis­{[1,2-bis­(diphenyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ2P,P′]silver(I)} dichloro­methane disolvate

✍ Scribed by Zhang, Dao-Peng ;Dou, Jian-Min ;Li, Da-Cheng ;Wang, Da-Qi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
181 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Ag 2 Cl 2 (C 26 H 30 B 10 P 2 ) 2 ]Á2CH 2 Cl 2 , was synthesized by the reaction of 1,2-bis(dipenylphosphino)-1,2dicarba-closo-dodecaborane with AgCl in ethanol. The diphosphino-closo-carborane ligand is coordinated in a bidentate manner to the Ag atom through the two P atoms. The coordination of the Ag atom is distorted tetrahedral, in which two vertices are formed by one chelating diphosphine ligand, and the other two are occupied by two bridging Cl atoms. The molecule is centrosymmetric.

📜 SIMILAR VOLUMES

Bis[μ-bis­(diphenyl­phosphino)methane-κ2
Bis[μ-bis­(diphenyl­phosphino)methane-κ2P:P′]bis­[(1,10-phenanthroline-κ2N,N′)copper(I)] bis­(tetra­fluoro­borate) dichloro­methane disolvate
✍ Liu, Huan-Yu ;Wang, Fen-Ying ;Wang, Guo-Yong ;Huang, Chang-Gan ;Peng, Da-Yong 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 160 KB

Bis[l-bis(diphenylphosphino)methane-j 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoroborate) dichloromethane disolvate

Di-μ-thio­cyanato-bis­{[1,1′-bis­(di­phe
Di-μ-thio­cyanato-bis­{[1,1′-bis­(di­phenyl­phosphino)­ferrocene-κ2P,P′]­copper(I)} di­chloro­methane disolvate
✍ Li, Dan ;Luo, Ya-Fang ;Wu, Tao ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

Single-crystal X-ray study T = 123 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.056 wR factor = 0.166 Data-to-parameter ratio = 17.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

catena-Poly[[(trifluoro­acetato-κO)silve
catena-Poly[[(trifluoro­acetato-κO)silver(I)]-μ-1,2-bis­(diphenyl­phosphino)ethane-κ2P:P′]
✍ Bao, Feng ;Lü, Xing-Qiang ;Ng, Seik Weng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 219 KB

In polymeric [Ag(C 2 F 3 O 2 )(C 26 H 24 P 2 )] n , the carboxylate is monodentate to silver, and the two diphosphine ligands that occupy different positions of 1 site symmetry link the Ag(C 2 O 2 F 3 ) units into a chain. The Ag atom shows trigonalplanar coordination.

Bis(μ-phenyl­phosphido-κ2P:P)­bis{[1,2-(
Bis(μ-phenyl­phosphido-κ2P:P)­bis{[1,2-(di­cyclo­hexyl­phosphino)­ethane-κ2P,P′]­platinum(I)} dichloride bis­(di­chloro­methane) hexane solvate
✍ Jaska, Cory A. ;Lough, Alan J. ;Manners, Ian 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 251 KB

Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.008 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.036 wR factor = 0.087 Data-to-parameter ratio = 23.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org