DFT Calculations of Triethyl and Trimethyl Orthoacetate Elimination Kinetics in the Gas Phase
✍ Scribed by Márquez, Edgar; Mora, José R.; Cordova, Tania; Chuchani, Gabriel
- Book ID
- 124154332
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 644 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
The gas-phase elimination kinetics of primary, secondary and tertiary b-hydroxynitriles were examined in static seasoned vessels over the temperature range 360-450 °C and pressure range 47-167 Torr (1 Torr = 133.3 Pa). These reactions are homogeneous, unimolecular and follow a first-order rate law.
## Abstract The kinetics of the gas‐phase elimination of benzaldoxime was determined in a static reaction system over the temperature and pressure range 350°C–400°C and 56–140 Torr, respectively. The products obtained were benzonitrile and water. The reaction was found to be homogeneous, unimolecul
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