Kinetics and Mechanisms of the Homogeneous, Unimolecular Gas-Phase Elimination of Trimethyl Orthoacetate and Trimethyl Orthobutyrate
✍ Scribed by Márquez, Edgar; Dominguez, Rosa; Tosta, María; Chuchani, Gabriel
- Book ID
- 127052656
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 75 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The kinetics of the gas‐phase elimination kinetics of CO~2~ from furoic acid was determined in a static system over the temperature range 415–455°C and pressure range 20–50 Torr. The products are furan and carbon dioxide. The reaction, which is carried out in vessels seasoned with allyl
## Abstract The kinetics of the gas‐phase elimination of benzaldoxime was determined in a static reaction system over the temperature and pressure range 350°C–400°C and 56–140 Torr, respectively. The products obtained were benzonitrile and water. The reaction was found to be homogeneous, unimolecul
The kinetics of the gas-phase elimination of several chloroesters were determined in a static svstem over the temperature range of 410-490OC and the pressure range of 47-236 torr. T h e reactions in seasoned vessels, and in the presence of a free-radical inhibitor, are homogeneous, unimolecular, and
Ethyl 4-chlorobutyrate, which is reexamined, pyrolyzes a t 350-410°C to ethylene, butyrolactone, a n d HC1. Under t h e reaction conditions, t h e primary product 4-chlorobutyric acid is responsible for the formation of y-butyrolactone and HCl. In seasoned vessels, and in the presence of a free-radi
## Abstract Theoretical studies on the gas phase elimination of 2‐substituted alkyl ethyl methylcarbonates were performed at the B3LYP/6‐31G\* and B3LYP/6‐31+__G__\*\* level of theory. The results of these calculations provide additional evidence that the mechanism of carbonates with a C~β~H bond