Gas Phase Elimination Kinetics of Methyl Mandelate: Experimental and DFT Studies
✍ Scribed by Rotinov, Alexandra; Escalante, Luz; Ramirez, Beatriz; Pereira, Desiree; Córdova, Tania; Chuchani, Gabriel
- Book ID
- 120014755
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 972 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
DL-Mandelic acid was pyrolyzed in a static reaction vessel over the temperature range 300•1-340•0 °C and pressure range of the substrate 15•2-52•1 Torr. The reaction, in a seasoned vessel and in the presence of the free radical inhibitor cyclohexene, is homogeneous, unimolecular and obeys a first-or
## Abstract The kinetics of the gas‐phase elimination kinetics of CO~2~ from furoic acid was determined in a static system over the temperature range 415–455°C and pressure range 20–50 Torr. The products are furan and carbon dioxide. The reaction, which is carried out in vessels seasoned with allyl