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Gas Phase Elimination Kinetics of Methyl Mandelate: Experimental and DFT Studies

✍ Scribed by Rotinov, Alexandra; Escalante, Luz; Ramirez, Beatriz; Pereira, Desiree; Córdova, Tania; Chuchani, Gabriel


Book ID
120014755
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
972 KB
Volume
113
Category
Article
ISSN
1089-5639

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📜 SIMILAR VOLUMES


ELIMINATION KINETICS OF DL -MANDELIC ACI
✍ Gabriel Chuchani; Ignacio Martin 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 42 KB 👁 2 views

DL-Mandelic acid was pyrolyzed in a static reaction vessel over the temperature range 300•1-340•0 °C and pressure range of the substrate 15•2-52•1 Torr. The reaction, in a seasoned vessel and in the presence of the free radical inhibitor cyclohexene, is homogeneous, unimolecular and obeys a first-or

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✍ Beatriz C. Ramírez; Rosa M. Domínguez; Armando Herize; María Tosta; Tania Cordov 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 256 KB

## Abstract The kinetics of the gas‐phase elimination kinetics of CO~2~ from furoic acid was determined in a static system over the temperature range 415–455°C and pressure range 20–50 Torr. The products are furan and carbon dioxide. The reaction, which is carried out in vessels seasoned with allyl