Maximally inhibited gas phase elimination kinetics of methyl 3-bromopropionate
✍ Scribed by Chuchani, G. ;Domínguez, R. M.
- Book ID
- 112683581
- Publisher
- Springer
- Year
- 1985
- Tongue
- English
- Weight
- 244 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0133-1736
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The gas phase elimination of methyl 4-chlorobutyrate and methyl 5-chlorovalerate has been reexamined, in a static system and seasoned vessel, over the temperature range of 419.6-472.1"C and pressure range of 45-108 tom. The reactions, under maximum inhibition with propene, are homogeneous, unimolecu
The elimination kinetics of the title compounds were carried out in a static system over the temperature range of 290-330°C and pressure range of 29.5-124 torr. The reactions, carried out in seasoned vessels with ally1 bromide, obey first-order rate law, are homogeneous and unimolecular. The tempera
The rates of gas-phase elimination reactions of methyl benzoylformate (1) and 3hydroxy-3-methyl-2-butanone (2) were obtained at T ϭ 600 K. The two substrates undergo unimolecular first-order elimination for which the Arrhenius equations are, respectively, log k ϭ 13.2 Ϫ 53270/(4.574 ϫ 600) for (1) a