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Development of Chiral Catalysts for Mukaiyama Aldol Reactions in Aqueous Media

✍ Scribed by Kitanosono, Taku; Kobayashi, Shū

Book ID
124063393
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
902 KB
Volume
14
Category
Article
ISSN
1527-8999

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Catalytic asymmetric Mukaiyama aldol rea
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Chiral copper(II)-catalyzed asymmetric aldol reactions of silyl enol ethers with aldehydes (the Mukaiyama aldol reaction) have been performed in an ethanol-water solution. The use of the protic solvent including water is a key to achieve these reactions. Moreover, a catalytic asymmetric aldol reacti

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Asymmetric aldol reactions in aqueous media have been realized by using zinc-based chiral Lewis acids. The aldol products have been obtained with high yield, diastereocontrol and a good level of enantioselectivity. The reactivity of both acetophenone and propiophenone enol ether surrogates was teste