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Catalytic asymmetric Mukaiyama aldol reactions in aqueous media

✍ Scribed by Shū Kobayashi; Satoshi Nagayama; Tsuyoshi Busujima

Book ID
104209477
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
499 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis

Chiral copper(II)-catalyzed asymmetric aldol reactions of silyl enol ethers with aldehydes (the Mukaiyama aldol reaction) have been performed in an ethanol-water solution. The use of the protic solvent including water is a key to achieve these reactions. Moreover, a catalytic asymmetric aldol reaction in pure water without using organic solvents has also been successfully carded out. This report has proposed and demonstrated a new concept for solvents in catalytic asymmetric aldol reactions.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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