Development of Building Blocks for the Synthesis of N-Heterocyclic Carbene Ligands
✍ Scribed by Xu, Guopin; Gilbertson, Scott R.
- Book ID
- 115456102
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 90 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1523-7060
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## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t
## Abstract magnified image Novel functionalized 1,3‐dialkylimidazolinium salts (LHCl) as NHC precursors have been prepared and successfully applied in palladium‐catalyzed arylation of benzaldehydes. The ortho position of aromatic aldehydes was directly and selectively arylated with aryl chlorides