The singlet-to-triplet intersystem crossing rate ( kST) of diphenylcarbene (DPC) is found to exhibit an inverse isotope effect in various solvents. An off-resonance coupling model between the initial singlet state and a sparse triplet vibronic manifold accounts for kST showing both an inverse isotop
β¦ LIBER β¦
Deuterium isotope effect on intersystem crossing for pheophytins
β Scribed by Kenneth J. Borowski; Robert E. Connors
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 360 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0047-2670
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