Temperature effect on inverse (Tn → S1) intersystem crossing
✍ Scribed by Hiroshi Fukumura; Koichi Kikuchi; Hiroshi Kokubun
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 322 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
The singlet-to-triplet intersystem crossing rate ( kST) of diphenylcarbene (DPC) is found to exhibit an inverse isotope effect in various solvents. An off-resonance coupling model between the initial singlet state and a sparse triplet vibronic manifold accounts for kST showing both an inverse isotop
It is shown that the interpretation of the experimental observations of Dewey and Hadley that led to the conclusion of the unexpectedly inefficient intersystem crossing St -TX process in 9,10-phenanthroline, and which prompted a new propeal by Azumi for the mechanism of intersystem crossing in N-het