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Determination of the rotational barrier of a chiral biphenyl: Comparison of theoretical and experimental data

โœ Scribed by Francesca Ceccacci; Giovanna Mancini; Paolo Mencarelli; Claudio Villani


Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
158 KB
Volume
14
Category
Article
ISSN
0957-4166

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## Abstract We synthesized numerous new monosubstituted dioxa[11]โ€paracyclophanes, which are planarโ€chiral atropisomers due to the hindered rotation of the bridge about the aromatic plane, and we were able to resolve the enantiomers of these compounds by enantioselective gas chromatography with sel