## Abstract For Abstract see ChemInform Abstract in Full Text.
Determination of the rotational barrier of a chiral biphenyl: Comparison of theoretical and experimental data
โ Scribed by Francesca Ceccacci; Giovanna Mancini; Paolo Mencarelli; Claudio Villani
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 158 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0957-4166
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The rotational barriers โฌG โก (T ) of the four atropisomeric polychlorinated biphenyls (PCBs) 2,2ะ,3,5ะ,6-pentachlorobiphenyl (PCB 95), 2,2ะ3,3ะ,4,6ะhexachlorobiphenyl (PCB 132), 2,2ะ,3,3ะ,6,6ะ-hexachlorobiphenyl (PCB 136), and 2,2ะ,3,4ะ,5ะ,6-hexachlorobiphenyl (PCB 149) were determined via on-line e
## Abstract We synthesized numerous new monosubstituted dioxa[11]โparacyclophanes, which are planarโchiral atropisomers due to the hindered rotation of the bridge about the aromatic plane, and we were able to resolve the enantiomers of these compounds by enantioselective gas chromatography with sel