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Atropisomerism, Biphenyls, and Fluorine: A Comparison of Rotational Barriers and Twist Angles

✍ Scribed by Frederic Leroux


Publisher
John Wiley and Sons
Year
2004
Weight
7 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Determination of the rotational barriers
✍ Volker Schurig; Sabine Reich πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 120 KB πŸ‘ 2 views

The rotational barriers ⌬G ‑ (T ) of the four atropisomeric polychlorinated biphenyls (PCBs) 2,2Ј,3,5Ј,6-pentachlorobiphenyl (PCB 95), 2,2Ј3,3Ј,4,6Јhexachlorobiphenyl (PCB 132), 2,2Ј,3,3Ј,6,6Ј-hexachlorobiphenyl (PCB 136), and 2,2Ј,3,4Ј,5Ј,6-hexachlorobiphenyl (PCB 149) were determined via on-line e