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Atropisomerism, Biphenyls, and Fluorine: A Comparison of Rotational Barriers and Twist Angles

✍ Scribed by Frédéric Leroux

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
135 KB
Volume
5
Category
Article
ISSN
1439-4227

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The rotational barriers ⌬G ‡ (T ) of the four atropisomeric polychlorinated biphenyls (PCBs) 2,2Ј,3,5Ј,6-pentachlorobiphenyl (PCB 95), 2,2Ј3,3Ј,4,6Јhexachlorobiphenyl (PCB 132), 2,2Ј,3,3Ј,6,6Ј-hexachlorobiphenyl (PCB 136), and 2,2Ј,3,4Ј,5Ј,6-hexachlorobiphenyl (PCB 149) were determined via on-line e