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Determination of the rotational barriers of atropisomeric polychlorinated biphenyls (PCBs) by a novel stopped-flow multidimensional gas chromatographic technique

✍ Scribed by Volker Schurig; Sabine Reich


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
120 KB
Volume
10
Category
Article
ISSN
0899-0042

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Determination of the rotational barriers
✍ Volker Schurig; Sabine Reich 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB 👁 2 views

The rotational barriers ⌬G ‡ (T ) of the four atropisomeric polychlorinated biphenyls (PCBs) 2,2Ј,3,5Ј,6-pentachlorobiphenyl (PCB 95), 2,2Ј3,3Ј,4,6Јhexachlorobiphenyl (PCB 132), 2,2Ј,3,3Ј,6,6Ј-hexachlorobiphenyl (PCB 136), and 2,2Ј,3,4Ј,5Ј,6-hexachlorobiphenyl (PCB 149) were determined via on-line e