Determination of the rate constants of the reactions of NO3 radical with CF3I and I(2P3/2)
โ Scribed by Yukio Nakano; Kengo Sadamori; Takashi Ishiwata
- Book ID
- 112136862
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 261 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21
The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine
Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO1 and FNO absorption transients, rate constants for reaction between CF90 and CFsO2 radicals with NO were determined, CFp02+NO+CF,O+N02 (3 ), CF,OtNO~CF,OtFNO(5).k~wasderivedtobe(1.68~0.26)X10~~'cm3molecuIe
The rate constants for the reactions CF302 + NO ~ CF30+NO 2 (1) and CF30+NO~ products (2) have been measured at room temperature using a fast flow reactor associated with a monitoring of CF30 radicals by laser induced fluorescence (LIF); for the measurement of k~, CF30 radicals are prepared by the d
The linear absorption cross-sections and photodissociation quantum yields for C F 3 N 0 have been measured at the wavelengths 694 3 and 632 8 nm (ruby and He-Ne lasers respectively) in a wide range of total pressure at T = 296 K The secondary reactions following the photolysis of C F 3 N 0 have been