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Determination of the rate constants of the reactions of NO3 radical with CF3I and I(2P3/2)

โœ Scribed by Yukio Nakano; Kengo Sadamori; Takashi Ishiwata


Book ID
112136862
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
261 KB
Volume
44
Category
Article
ISSN
0538-8066

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Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21

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The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine

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Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO1 and FNO absorption transients, rate constants for reaction between CF90 and CFsO2 radicals with NO were determined, CFp02+NO+CF,O+N02 (3 ), CF,OtNO~CF,OtFNO(5).k~wasderivedtobe(1.68~0.26)X10~~'cm3molecuIe

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โœ C. Bourbon; M. Brioukov; B. Hanoune; J.P. Sawerysyn; P. Devolder ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 598 KB

The rate constants for the reactions CF302 + NO ~ CF30+NO 2 (1) and CF30+NO~ products (2) have been measured at room temperature using a fast flow reactor associated with a monitoring of CF30 radicals by laser induced fluorescence (LIF); for the measurement of k~, CF30 radicals are prepared by the d

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โœ A. B. Garmanov; A. B. Vakhtin ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 456 KB ๐Ÿ‘ 2 views

The linear absorption cross-sections and photodissociation quantum yields for C F 3 N 0 have been measured at the wavelengths 694 3 and 632 8 nm (ruby and He-Ne lasers respectively) in a wide range of total pressure at T = 296 K The secondary reactions following the photolysis of C F 3 N 0 have been