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Determination of Rate Constants of N-Alkylation of Primary Amines by 1 H NMR Spectroscopy

✍ Scribed by Li, Chenghong

Book ID
121387478
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
723 KB
Volume
117
Category
Article
ISSN
1089-5639

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## Abstract The pK a values of N-alkyl-N,N-dimethylamine-N-oxides were determined from the pH dependences of chemical shifts in 1H NMR and 13C NMR spectra. The dependences were measured at concentrations below and above the critical micelle concentration of the amine oxides. Above the critical mice