An electron paramagnetic resonance (EPR) technique was used to show that simple alkyl radicals readily abstract hydrogen from l,4-cyclohexadiene. Rate constants for the reaction were ca. 104-105 M-' s-' at 300 K and activation energies 5-7 kcal mol-'. For the stabilized radicals, ally1 and benzyl, t
Absolute Rate Constants for the Reactions of Primary Alkyl Radicals with Aromatic Amines 1
β Scribed by Burton, Alan; Ingold, K. U.; Walton, J. C.
- Book ID
- 125900533
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 135 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
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