## Abstract Cyano‐substituted methyl radicals (cyanomethyl–hand 2‐cyano‐2‐propyl radicals) and __syn__‐and __anti__‐1‐cyano‐allyl radicals were generated, and their recombination kinetics in solution were investigated between −50 and +50°C by time‐resolved electron‐spin‐resonance spectroscopy. The
Rate constants for chalcogen group transfers in bimolecular substitution reactions with primary alkyl radicals
✍ Scribed by Curran, Dennis P.; Martin-Esker, Amanda A.; Ko, Sung Bo; Newcomb, Martin
- Book ID
- 127046949
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 629 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Relative rate constants for the reactions of hydroxyl radicals with a series of alkyl substituted olefins were measured by competitive reactions between pairs of olefins a t 298 r 2 K and 1 atmospheric pressure. Hydroxyl radicals were produced by the photolysis of H,O, with 254-nm irradiation. The o
Rate constants for 6-exo cyclization of the 7,7-diphenyl-6-heptenyl radical (3) in benzotrifluoride (BTF, PhCF3) were determined by laser flash photolysis, and radical clock 3 was used in competition kinetic studies for determination of rate constants of reactions of the fluorous tin hydride reagent