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Rate constants for reaction of a fluorous tin hydride reagent with primary alkyl radicals

โœ Scribed by John H. Horner; Felix N. Martinez; Martin Newcomb; Dennis P. Curran

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
224 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Rate constants for 6-exo cyclization of the 7,7-diphenyl-6-heptenyl radical (3) in benzotrifluoride (BTF, PhCF3) were determined by laser flash photolysis, and radical clock 3 was used in competition kinetic studies for determination of rate constants of reactions of the fluorous tin hydride reagent tris(2-(perfluorohexyl)ethyl)tin hydride with primary alkyl radicals.

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