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Detection of PO, Cl and P from the photodissociation of POCl3 at 193 nm

✍ Scribed by Deirdre A. Belle-Oudry; Sunita Satyapal; Thibaud Mussillon; Paul L. Houston

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 471 KB
Volume: 235
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00115-k

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✦ Synopsis

The photodissociation of POCI 3 has been investigated using the unfocused radiation of an excimer operating at 193 nm. PO, P and C1 radicals were probed by resonance-enhanced multiphoton ionization, and signal intensities were studied as a function of excimer laser power. The probe laser was found to produce a non-resonant PO + background signal in addition to the resonant ionization signal of neutral PO. A set of possible dissociation pathways has been postulated.

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