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Branching ratio for S(33Pj) AND S(31D2) atom production in the photodissociation of CS2 at 193 nm

✍ Scribed by Graham Black; Leonard E. Jusinski

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 288 KB
Volume: 124
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)85019-9

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✦ Synopsis

Resonance-enhanced photoionization has been used to follow S(3P,) in the photodissociation of CS, at 193 nm. The contributions from initial photodissociation and from S('D) relaxation have been resolved and give a (15 f 5)X yield of S('D). The possibility of secondary production of S(3P,) by CS photodissociation with a second 193 nm photon is discussed. Although thrs might raise the S('D) yield to (26 f 8)%, production of S(3P,) is still the dominant photodissociation channel.

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