✦ LIBER ✦

Photodissociation of H2S and the HS radical at 193.3 nm

✍ Scribed by R.E. Continetti; B.A. Balko; Y.T. Lee

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 540 KB
Volume: 182
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)90097-s

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✦ Synopsis

Photodissociation of H$ has been studied at 193.3 nm using H atom photofragment-translational speclroscopy with massspectrometric detection. H t HS( v) product branching ratios are reported which are not in quantitative agreement with other recent experimental results. Secondary photodissociation of HS radicals has also been observed, showing that both S( 'P) and S ('D) are produced via perpendicular transitions. The HS bond energy was found to be 3.62 k 0.03 eV.

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