Dehydrogenative Silylation of Terminal Alkynes Catalyzed by Ytterbium−Imine Complexes
✍ Scribed by Takaki, Ken; Kurioka, Masanobu; Kamata, Tohru; Takehira, Katsuomi; Makioka, Yoshikazu; Fujiwara, Yuzo
- Book ID
- 126472165
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 60 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0022-3263
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Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl-and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions.