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ChemInform Abstract: Ytterbium(II)-Aromatic Imine Dianion Complexes-Catalyzed Isomerization of Terminal Alkynes.

✍ Scribed by Y. MAKIOKA; A. SAIKI; K. TAKAKI; Y. TANIGUCHI; T. KITAMURA; Y. FUJIWARA

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199726059

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Ruthenium-Catalyzed Dimerization of Terminal Alkynes Initiated by a Neutral Vinylidene Complex. -The catalytic coupling of alkynes (III) or (VI) in the presence of Ru complexes such as (I) or (II) leads to butenynes with both conversion and selectivity strongly depending on the alkyne substituent.