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Dehydrogenative Silylation of Amines and Hydrosilylation of Imines Catalyzed by Ytterbium−Imine Complexes

✍ Scribed by Takaki, Ken; Kamata, Tohru; Miura, Yoshimi; Shishido, Tetsuya; Takehira, Katsuomi

Book ID
127145555
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
77 KB
Volume
64
Category
Article
ISSN
0022-3263

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Hydrosilylation of olefins and dehydroge
Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide–imine complexes
✍ Ken Takaki; Kentaro Sonoda; Takeshi Kousaka; Go Koshoji; Tetsuya Shishido; Katsu 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 84 KB

Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl-and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions.