✦ LIBER ✦

Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide–imine complexes

✍ Scribed by Ken Takaki; Kentaro Sonoda; Takeshi Kousaka; Go Koshoji; Tetsuya Shishido; Katsuomi Takehira

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 84 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)02027-5

No coin nor oath required. For personal study only.

✦ Synopsis

Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl-and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions.

📜 SIMILAR VOLUMES

ChemInform Abstract: Hydrosilylation of

ChemInform Abstract: Hydrosilylation of Olefins and Dehydrogenative Double Silylation of Conjugated Dienes Catalyzed by Lanthanoid—Imine Complexes.

✍ Ken Takaki; Kentaro Sonoda; Takeshi Kousaka; Go Koshoji; Tetsuya Shishido; Katsu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

ChemInform Abstract: Dehydrogenative Sil

ChemInform Abstract: Dehydrogenative Silylation of Amines and Hydrosilylation of Imines Catalyzed by Ytterbium—Imine Complexes.

✍ Ken Takaki; Tohru Kamata; Yoshimi Miura; Tetsuya Shishido; Katsuomi Takehira 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Platinum complex-catalyzed dehydrogenati

Platinum complex-catalyzed dehydrogenative double silylation of olefins and dienes with o-bis(dimethylsilyl)benzene

✍ Masato Tanaka; Yuko Uchimaru; Hans-Jürgen Lautenschlager 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 808 KB

Stereospecific 1,4-cis-Hydrogenation of

Stereospecific 1,4-cis-Hydrogenation of Conjugated Dienes, Dienynes, and Dienediynes Catalyzed by Chromium Carbonyl Complexes in Stereocontrolled Syntheses of Physiologically Active Olefins

✍ A. A. Vasil'ev; E. P. Serebryakov 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 54 KB