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Platinum complex-catalyzed dehydrogenative double silylation of olefins and dienes with o-bis(dimethylsilyl)benzene

✍ Scribed by Masato Tanaka; Yuko Uchimaru; Hans-Jürgen Lautenschlager

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
808 KB
Volume
428
Category
Article
ISSN
0022-328X

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Hydrosilylation of olefins and dehydroge
Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide–imine complexes
✍ Ken Takaki; Kentaro Sonoda; Takeshi Kousaka; Go Koshoji; Tetsuya Shishido; Katsu 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 84 KB

Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl-and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, under similar conditions.