## Abstract Chemically activated acetyl radicals, with an excitation energy of 78 kJ/mole, were formed by the addition of methyl radicals to carbon monoxide. At 273Β·K the pressure required to stabilize one half of the excited radicals was 500 torr. From measurements of the acetyl radical yield at p
Decomposition of chemically activated monochloroethyl radicals
β Scribed by Le-Khac Huy; W. Forst; J.A. Franklin; G. Huybrechts
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 310 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The rate constant for the unimolecular decomposition of chemically activated monochioroethyl radicals has been calculated at 310Β°K using RRKM theory. The result obtained is in satisfactory agreement with the experimental value.
PRYSICS LETTERS May 1969
chloroethyl radicals, satisfactory results are obtained without any tampering with the frequencies of the complex.
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