✦ LIBER ✦

On the nonstatistical character of chemically activated CHF2Cl* and CHF3* decomposition

✍ Scribed by V.I. Vedeneev; A.I. Voronin; M.A. Teitelboum

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 329 KB
Volume: 34
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)80203-x

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✦ Synopsis

The RRKM theory and thz quantumraiation of RRK theory are used to c~lculare the decomposition rate constants of chemically activated CHFzCl and CHF,. The calculated values of the rate constants are compared with cxperimcntal datn.

It is shown that the decompositions of CHFS and CHFzCt* proceed much fxster than they should in terms of statistical the-Oiy.

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