On the partial double-bond character of the C-F bond in CH3F, CH2F2 and CHF3 : ab initio result
β Scribed by Tae-Kyu Ha
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 290 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
In view of the experimental determination of the NF bond length in NF: by Christe et al. (197 1) it is worthwhile to attempt to predict the NF bond length in N2 F+ , the NF bond with the largest known NF force constant. Calculations at the HF/4-3 1 G, HF/6-3 lG\* and MP2/6-3 IG\* levels were complet
The kinetics of the gas-phase reaction of CH3F with 12 have been studied spectrophotometrically from 629 to 710 K, and were determined to be consistent with the following mechanism: (KIJ squares analysis of the kinetic data taken in the initial stages of reaction resulted in log k4 (M-w) = (11.3 f
## Abstract The bondβformation processes between the d^10^ metal fragments Ni(PR~3~)~2~ (R = H, CH~3~, F, CF~3~, Ph) and acetylene have been studied by density functional theory with the BP86 functional and large TZV(2df,2pd) basis sets. The Niβacetylene bonds have been analyzed in terms of distort