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The unimolecular decomposition and isomerization of chemically activated 1-methyl-2,2,3,3-tetrafluorocyclopropane

✍ Scribed by G. Arbilla; J. C. Ferrero; E. H. Staricco

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
591 KB
Volume
24
Category
Article
ISSN
0538-8066

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✦ Synopsis

The reaction of CHZ('A1) with 1,1,2,2-tetrafluorocyclopropane was studied at 300 K and a t pressures between 9.0 and 365.0 torr. Chemically activated 1-methyl-2,2,3,3-tetrafluorocyclopropane was formed and two competitive reaction paths, namely decomposition and isomerization, were observed. By fitting the experimental results to calculated values from RRKM theory, we estimated the Arrhenius parameters for both reaction processess as well as the heat of formation of 1-methyl-2,2,3,3-tetrafluorocyclopropane.

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